Remoción de ácido 2,4-diclorofenoxiacético en solución acuosa mediante biomateriales a base de quitosano y residuos de naranja
DOI:
https://doi.org/10.65093/aci.v16.n2.2025.26Palabras clave:
adsorción, herbicida, biopolímero, cáscara de cítricosResumen
Entre los contaminantes más comunes en suelos y cuerpos de agua se encuentran los derivados de actividades agrícolas. El ácido 2,4-diclorofenoxiacético (2,4-D) es un compuesto perteneciente al grupo de los fenoxis y se utiliza ampliamente como herbicida selectivo. Debido a su naturaleza ionizable, puede migrar fácilmente hacia los cuerpos de agua, representando un riesgo ambiental. Una alternativa viable y económica para su remoción es la adsorción mediante biomateriales, que combinan propiedades fisicoquímicas de sus componentes para obtener características estructurales y funcionales mejoradas. En este estudio, se sintetizaron biomateriales basados en quitosano y cáscara de naranja mediante reticulación iónica. Los experimentos de adsorción de 2,4-D se realizaron a valores de pH de 3 y 5, a 25 °C y se obtuvo una capacidad máxima de adsorción de 8.3 mg g-1 a pH 3. Los biomateriales se caracterizaron mediante diversas técnicas para analizar sus propiedades estructurales y los posibles mecanismos de interacción.
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